Exercises in molecular gymnastics--bending, stretching and twisting porphyrins.

نویسنده

  • Mathias O Senge
چکیده

The functional versatility of tetrapyrroles as natural cofactors is related to their conformational flexibility where manipulation of the macrocycle conformation allows a fine-tuning of their physicochemical properties. This feature article gives a personal account of the synthesis and solid state structural characterization of highly substituted, non-planar porphyrins. Their conformational analysis identifies sterically strained tetrapyrroles as a versatile class of biomimetic compounds with tailor-made properties.

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عنوان ژورنال:
  • Chemical communications

دوره 3  شماره 

صفحات  -

تاریخ انتشار 2006